Gather the ingredients. Line a baking sheet with parchment paper or waxed paper.
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In a large mixing bowl, combine the powdered sugar, creamy peanut butter, melted butter, vanilla extract, and salt until smooth.
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Scoop and shape into 1-inch balls. Place on the prepared baking sheet and chill until firm, at least 20 minutes.
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Place the chocolate chips and vegetable shortening in a microwave-safe bowl. Microwave in 30-second intervals, stirring each time, until the mixture is completely melted and smooth.
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Insert a toothpick in the top center of a chilled peanut butter ball.
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Dip the ball into the melted chocolate, about 3/4 of the way, leaving a circle of peanut butter visible on top. Allow the excess chocolate to drip off into the bowl, then place the buckeye back on the baking sheet.
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Remove the toothpick and carefully smooth over the hole. Repeat with the remaining peanut butter balls and chocolate. If chocolate thickens as you are dipping the buckeyes, microwave in 10-second intervals until it achieves the desired consistency when stirred.
Chill again until the buckeyes are firm and the chocolate is set, at least 30 minutes.
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Serve chilled straight from the refrigerator or at room temperature. Refrigerate in an airtight container for up to 5 days or freeze for up to 3 months.
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Enjoy!